Photochemical Reaction of Cholest-4-ene-3, 6-dione
نویسندگان
چکیده
منابع مشابه
6-Methylideneandrost-4-ene-3,17-dione
In the title compound, C(20)H(26)O(2), which is the 6-methyl-ene derivative of androstenedione and a synthetic percursor of exemestane, the steroid A ring approximates to a sofa (or envelope) conformation, with the methyl-ene group adjacent to the link to the B ring lying out of the plane of the other atoms. The B and C rings have slightly flattened chair conformations and the D ring is an enve...
متن کامل3-Methyl-5α-cholest-2-ene
In the title cholestane derivative, C(28)H(48) [systematic name: (1S,2S,7R,10R,11R,14R,15R)-2,5,10,15-tetra-methyl-14-[(2R)-6-methyl-heptan-2-yl]tetra-cyclo-[8.7.0.0(2,7).0(11,15)]hepta-dec-4-ene], the cyclo-hexene ring adopts a half-chair conformation. The parent 5α-cholest-2-ene and the equivalent fragment of the title compound are almost superimposable (r.m.s. deviation = 0.033 Å).
متن کاملCholest-5-ene
The asymmetric unit of the title compound, C(27)H(46), contains two crytallographically independent cholest-5-ene mol-ecules (A and B). In each mol-ecule, the three six-membered rings are all in chair conformations, while the five-membered ring is in a twist conformation. The terminal isopropyl group of mol-ecule A has a (-)-gauche conformation, whereas that of mol-ecule B has a (+)-gauche conf...
متن کامل6 - ( 1 , 3 - Dihydroxy - 3 - phenylpropylidene ) - 5 - hydroxy - 2 , 2 , 4 - trimethylcyclohex - 4 - ene - 1 , 3 - dione
A novel compound involved in the aroma of the fruit Campomanesia lineatifolia was isolated; the structure was determined by spectroscopic methods, mainly 1D and 2D NMR.
متن کامل11α,15α-Dihydroxyandrost-4-ene-3,17-dione
The title compound, C(19)H(26)O(4), was biotransformed from androstenedione. In the crystal, inter-molecular O-H⋯O hydrogen bonds link molecules into a corrugated sheet, which lies parallel to the ab plane. Ring A has a slightly distorted half-chair conformation, rings B and C adopt chair conformations, while the cyclo-pentane ring D adopts a 14α-envelope conformation.
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ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 1968
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi1947.88.1_98